The Science of Roman Candles and Catherine Wheels: Investigating Fireworks

The Science of Roman Candles and Catherine Wheels: Investigating Fireworks


Fireworks are an enchanting phenomenon, admired by many yet often feared by felines due to their innate dislike for loud sounds. In addition to their mesmerizing exhibition against the dark sky, fireworks act as an intriguing showcase of explosive chemistry.

In the realm of fireworks, chemical reactions propel the explosive flashes and brilliant hues, mainly through the interactions of elements found on the periodic table. Elements such as oxygen, chlorine, and fluorine, recognized for being “greedy” with electrons, can react with great intensity when paired in specific ways. When these elements connect with one another, they generate unstable compounds, like chlorine trifluoride, which reacts explosively with nearly anything.

Oxygen gas, typically stable in its usual state, will quickly react with fuels upon ignition, producing water and carbon dioxide. Peroxides, containing single oxygen bonds, are more reactive and demand cautious handling. Hydrogen peroxide, present in many households, is stable at low concentrations but poses risks at elevated levels.

A crucial element in fireworks is oxidizers like nitrates, which facilitate combustion. Perchlorates, though more stable than chlorates, are favored for their predictable explosive responses. The combination of fuel and oxidizer in fireworks results in the explosive force when ignited, with binders such as dextrin keeping the mixture intact.

The brilliant colors seen in fireworks stem from metal salts including sodium, strontium, and barium. These metals give off distinctive colors when heated, as their electrons absorb energy and subsequently release it as light. This radiation emission exemplifies quantum chemistry, leading to the varied spectrum of colors in the night sky.

Despite their joy, fireworks can pose ecological risks, such as perchlorate pollution in aquatic environments. Nevertheless, natural bacteria are capable of transforming perchlorates into benign substances, reducing potential threats.

As fireworks brighten the nighttime, they stand as a testimony to the elegance and power of chemistry, offering a breathtaking display of colors and reactions.