A ruthenium sandwich can switch on iodobenzene’s halogen-bonding ability, increasing iodine’s σ-hole potential eight-fold. Similar to hydrogen bonds, halogen bonds are non-covalent interactions. They form between a covalently-bonded halogen atom’s electrophilic region – the σ-hole – and a nucleophilic region in another (or the same) molecule. Halogens with a bigger σ-hole potential are better halogen-bond […]
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